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Beilstein J. Org. Chem. 2012, 8, 2085–2090, doi:10.3762/bjoc.8.234
Graphical Abstract
Scheme 1: Retrosynthetic strategies for (−)-viridic acid (1) and analogues by (a) a bidirectional peptide-cou...
Scheme 2: Reactions and conditions: (a) Boc-Gly-OH, EDCI, HOAt, TEA, CH2Cl2, rt, 20 h, 73%. (b) LiOH, THF/H2O...
Scheme 3: Reactions and conditions: (a) H-Gly-OBn·HCl, NMM, ethyl chloroformate, CHCl3, 18 h, rt, 88%. (b) H2...